📖 Explanation
Given: molecular weight of CaHbOcNd=187gm Solution of compound in distilled water =935mg/t
TOCCODTKN=360mg/lt( as C)=600mg/tt( as O2)=140mg/lt(As N)
CaHbOc Nd+4(4a+b−2c−3 d)O2→aCO2+2b−3 dH2O+dNH3 Now, d= Atomic weight of N(935140×187)=14935140×187=2 a=12935360×187=6 Now, 44a+b−2c−3d= Atomic weight of O2(935660×187)=32(935600×187)
44×6+b−2c−3×2b−2c=3.75=−3(i)
Now, Molecular water of compound (CaHbOcNd)=187
12a+b×1+16c+14d=18712×6+b+16c+14×2=187
b+16c=87(ii) On solving equation (i) and (ii), we get
b=7c=5
Hence, a=6,b=7,c=5,d=2 Correct options are (A), (B) and (C).