📖 Explanation
According to the de Broglie hypothesis, the circumference of an electron's orbit corresponds to an integer multiple of its wavelength, given by the relationship 2πrn=nλn. By rearranging this formula to solve for the wavelength, we find that λn=n2πrn. Since the orbital radius of an electron in a hydrogen atom is proportional to the square of the principal quantum number, or rn∝n2, we can substitute this into our wavelength expression to see that λn∝nn2, which simplifies to a linear proportionality where λn∝n.
For the ground state, where n=1, the orbital radius is r1=5.3×10−11 m. For the third excited state, where n=4, the radius is r4=8.48×10−10 m. Using the simplified proportionality λn∝n, the ratio of the wavelength in the third excited state to the ground state is calculated as λ1λ4=14=4. Verifying this with the given radii, λ1=12π(5.3×10−11) and λ4=42π(8.48×10−10). Substituting 8.48×10−10 m as 16×5.3×10−11 m into the second equation gives λ4=42π(16×5.3×10−11)=8π(5.3×10−11) m, which confirms that the wavelength in the excited state is 4 times larger than in the ground state.